field in de Sitter spacetime has an infrared divergence [42–44, 46] in the mass going to zero limit. The term
corresponding to the infrared divergence has no spacetime dependence and it provides a dominant secular
contribution to the response rate of the detector.
We also consider massless scalar fields in radiation dominated spacetime and matter dominated spacetimes
to study detector response in other epochs of cosmological expansion. For these cases, we make use of an
equivalence between massless scalar fields in FRW spacetimes with that of massive scalar fields in de Sitter
spacetime [32, 47, 48]. Using this equivalence, we place massless scalar fields in FRW spacetimes in the Bunch
Davies like vacuum of the corresponding massive scalar field in de Sitter spacetime. The Wightman function
of massless fields in matter dominated cases inherit the infrared divergence of the de Sitter spacetime but
now with a time dependent conformal factor multiplying the divergent term [32, 47]. Thus, we find that the
term corresponding to the infrared divergence provides the dominant contribution to the transition response
rate. For radiation dominated case, the massless scalar field correlator does not possess any such infrared
divergent term and hence provides finite detector response.
The analysis shows that the infrared divergences of the de Sitter and matter dominated spacetimes man-
ifest themselves in the detector response. However, in de Sitter spacetime the divergence of correlators is
sometimes argued to be originated from breaking of de Sitter symmetry [40, 42] and any physically sensible
result should be free of any divergences. A line of argument to that end is to regard only those operators
as physical which are infrared finite. For example, [49] argues that the shift invariant operators like the
differences of the field operators, derivatives of fields etc., are to be regarded as true physical observables
as they are infrared finite for massless scalar fields in de Sitter spacetime. Similarly, the derivatives present
in the stress energy operator also renders it infrared finite for the de Sitter spacetime [50]. Keeping these
arguments in mind, we look at the response of more ’physical’ derivatively coupled UdW detectors.
In the derivative coupling case, the detector couples to the derivative of the field with respect to the proper
time along the trajectory [7]. For this case, the response rate of transition between quantum states of the
detector depends upon the double derivative of the Wightman function of the field with respect to the proper
time at different points along the detector’s trajectory [7, 51]. In the case of de Sitter spacetime, under the
action of the derivatives, this term goes away as the infrared divergent term in the Wightman function for
nearly massless scalar fields does not have any spacetime dependence. Thus the transition response rate
of derivatively coupled UdW detector for nearly massless scalar fields in de Sitter spacetime remains finite.
However, in the case of massless scalar fields in matter dominated spacetimes, the infrared divergent term
has time dependence and it does not vanish under the action of derivatives with respect to the detector’s
proper time and provides the dominant contribution to the response rate. Thus, even though the derivative
coupling could cure the infrared divergence of the de Sitter spacetime, this does not happen for the matter
dominated spacetimes. Using this we argue that the realistic physical systems, e.g. the derivatively couple
UdW detectors are expected to capture the revival of quantum correlations in the matter dominaated era of
the universe.
In addition to these formal analyses of UdW detectors and derivatively coupled UdW detectors for quantum
scalar fields in the considered spacetimes, we investigate the scenario of the coupling of hydrogen atoms with
gravitational waves where a derivatively coupled UdW like coupling occurs. Following the treatment given
in [52, 53], we consider the interaction of a non-relativistic hydrogen atom (whose center of mass is moving
along some time-like classical trajectory) with the curvature of the spacetime. Considering gravitational
wave perturbations over the homogeneous and isotropic FRW backgrounds, one can find the form of the
above interaction term upto to leading order in gravitational perturbations. The interaction between gravi-
tational waves and hydrogen atom has the form of a generalized derivatively coupled UdW detector. For this
setting, the above analysis of the response rate of derivatively coupled UdW detector in matter dominated
spacetimes can be carried over and the implications of the dominant infrared term on the transition of the
electron of the atom between its different atomic states can be investigated. Such an analysis also provides
a potential avenue to look for observational signatures of quantized gravitational waves.
The rest of the paper is divided in four sections. In section II, we consider conventional UdW detectors for
scalar fields in de Sitter, radiation-dominated and matter-dominated spacetimes and calculate the response
rate for them. In section III, we perform a similar analysis as is done in section II but for derivatively coupled
UdW detectors. In section IV, we consider a specific UdW coupling where the detector couples with the
stress energy tensor of the field. In this section, we also look at the dynamics of a hydrogen atom in FRW
spacetimes with and without gravitational wave perturbations which harbours a derivatively coupled UdW
3