2
I. INTRODUCTION
As a relativistic effect, the motion of an electron in an elec-
tric field creates a magnetic field in its rest frame (Jackson,
1998). The resulting spin-orbit coupling (SOC) in solid-state
systems can have different contributions. In addition to the
coupling of electron spin with the average electric field from
the periodic crystal potential, other SOC terms arise due to
an applied or built-in electric field, for example due to broken
inversion symmetry. One can also distinguish intrinsic, ex-
trinsic, and synthetic SOC, due to electronic structure, impuri-
ties, and magnetic textures, respectively. With SOC, at a given
wave vector, k, the twofold spin degeneracy is removed result-
ing in a k-dependent Zeeman energy and an effective magnetic
field (Winkler, 2003; Žuti´
cet al., 2004). In superconducting
heterostructures, the role of SOC can be even more striking
by transforming the orbital and spin symmetry of the Cooper
pairs, through which exotic states may emerge—even from
simple s-wave spin-singlet superconductors.
For decades, SOC effects have been identified as crucial
for many normal-state phenomena, such as spin-photon and
spin-charge conversion (Meier and Zakharchenya, 1984), var-
ious topological states (Armitage et al., 2018; Shen, 2012),
the family of spin Hall effects (D’yakonov and Perel’, 1971a;
Maekawa et al., 2012), magnetocrystalline anisotropy and
noncolinear spin textures (including skyrmions and chiral do-
main walls) (Tsymbal and Žuti´
c, 2019). They also formed the
basis for early spintronic applications, which can be traced
back to the discovery of anisotropic magnetoresistance in
1857 (Thomson, 1857; Žuti´
cet al., 2004). In contrast, the
relevance of SOC in superconducting structures was largely
absent, or limited to specific aspects without fully recogniz-
ing many connections (Bergeret et al., 2005; Buzdin, 2005;
Golubov et al., 2004; Meservey and Tedrow, 1994; Tedrow
and Meservey, 1971). Motivated by recent advances in stud-
ies of hybrid superconducting structures where SOC plays a
prominent role, this review aims to provide an experimental
and theoretical framework to highlight many such connec-
tions between different phenomena and emerging applications
in these structures.
The quest to realize topological superconductivity and elu-
sive Majorana states for fault-tolerant topological quantum
computing in structures with strong SOC relies on equal-spin-
triplet superconductivity (Elliot and Franz, 2015; Nayak et al.,
2008). This triplet superconductivity is also sought in super-
conducting spintronics (Eschrig, 2015; Linder and Robinson,
2015; Ohnishi et al., 2020; Yang et al., 2021) as it supports
dissipationless spin currents and allows for the coexistence of
superconductivity and ferromagnetism. Josephson junctions
(JJs) with tunable SOC, which enable spin-triplet supercon-
ductivity, are important building blocks for topological super-
conductivity and superconducting spintronics (Dartiailh et al.,
2021; Mayer et al., 2020). These JJs also reveal the supercon-
ducting diode effect (Baumgartner et al., 2022; Dartiailh et al.,
2021) an example of a nonreciprocal phenomenon (Nadeem
et al., 2023). While nonreciprocal effects are technologi-
cally important (Marder, 2010; Shockley, 1952) and known
since the nineteenth century in the normal state (Faraday,
1846; Kerr, 1877), experimental demonstrations of supercon-
ducting counterparts were largely absent, until a few years
ago (Nadeem et al., 2023). Analogous to multiferroic ma-
terials which allow electrical control of magnetic properties
and, conversely, magnetic control of electrical properties, we
can view SOC in the superconducting state as enabling vari-
ous magnetoelectric effects (Tkachov, 2017) and facilitating
the coupling between different order parameters. Since SOC
changes the properties of quasiparticles in superconductors, it
has also been shown to produce strongly enhanced spin Hall
phenomena in superconducting structures.
With controllable SOC, the previous efforts to integrate
superconductors and ferromagnets can be radically simpli-
fied. Instead of engineering complex noncollinear mag-
netic structures at the superconductor/ferromagnet (S/F) inter-
face (Banerjee et al., 2014; Keizer et al., 2006; Khaire et al.,
2010; Robinson et al., 2012, 2010; Usman et al., 2011), a sin-
gle common F with SOC in a superconducting heterostruc-
ture with broken inversion symmetry is sufficient to support
spin-triplet superconductivity and large magnetoresistive ef-
fects (Banerjee et al., 2018; Cai et al., 2021; González-Ruano
et al., 2021, 2020; Jeon et al., 2018, 2019a, 2020b; Martínez
et al., 2020). Theoretically, the observed role of SOC in
singlet-to-triplet pair conversion has been studied for both
ballistic and diffusive transport (Bergeret and Tokatly, 2013,
2014; Feng et al., 2008; Högl et al., 2015; Jacobsen et al.,
2015; Yokoyama et al., 2006) and preceded by the related
effect of spin-active interfaces (Eschrig et al., 2003; Hal-
terman and Valls, 2009; Linder et al., 2009; Žuti´
c and Das
Sarma, 1999) and SOC generated k-anisotropic triplet con-
densates (Edelstein, 2003; Gor’kov and Rashba, 2001).
Another example where SOC fundamentally modifies the
underlying physics is within superconducting random-access
memories using ferromagnetic JJs. Here, nonvolatile control
of the zero and πground state phase encoding binary informa-
tion (Birge and Houzet, 2019; Dayton et al., 2018), needs to
be revisited in the presence of SOC where, in addition to the
spin-singlet and the spin-triplet states, their admixture is also
possible. The resulting anomalous Josephson effect (Buzdin,
2008; Reynoso et al., 2008) supports an arbitrary phase shift
other than just zero and π, leading to novel challenges and
opportunities for non-binary information processing and stor-
age. Just as magnetic JJs are the building blocks for super-
conducting memories, their nonmagnetic counterparts are the
key elements for low-power and high-speed superconducting
logic (Holmes et al., 2013; Tafuri, 2019) and superconduct-
ing quantum computing (Krantz et al., 2019; Wendin, 2017).
This means that SOC may not only modify such devices, but
also provide entirely new functionalities in their operation, as
current-phase relation, Josephson energy, critical temperature
and critical current, can all strongly change with SOC. As
in the normal state, SOC is the major source of spin relax-
ation and decoherence, as well as the underlying mechanism
for spin dynamics, in the superconducting state (Žuti´
cet al.,