Incandescent temporal metamaterials

2025-04-24 0 0 8.44MB 43 页 10玖币
侵权投诉
Incandescent temporal metamaterials
J. Enrique V´azquez-Lozanoand I˜nigo Liberal
Department of Electrical, Electronic and Communications Engineering,
Institute of Smart Cities (ISC), Universidad P´ublica de Navarra (UPNA), 31006 Pamplona, Spain
(Dated: October 12, 2022)
Regarded as a promising alternative to spatially shaping matter, time-varying media can be
seized to control and manipulate wave phenomena, including thermal radiation. Here, based
upon the framework of macroscopic quantum electrodynamics, we elaborate a comprehensive
quantum theoretical formulation that lies the basis for investigating thermal emission effects in
time-modulated media. Our theory unveils new physics brought about by time-varying media:
nontrivial correlations between thermal fluctuating currents at different frequencies and positions,
thermal radiation overcoming the black-body spectrum, and quantum vacuum amplification effects
at finite temperature. We illustrate how these features lead to striking phenomena and novel
thermal emitters, specifically, showing that the time-modulation releases strong field fluctuations
confined within epsilon-near-zero (ENZ) bodies, and that, in turn, it enables a narrowband
(partially coherent) emission spanning the whole range of wavevectors, from near to far-field regimes.
On the basis of the latest scientific and technological
breakthroughs in nanophotonics and material science,
the development of metamaterials have brought forth
an ideal playground for engineering innovative forms of
light-matter interactions [1]. In the quest for reaching
an increasing control over wave phenomena, a new
burgeoning approach consists in harnessing time as an
additional degree of freedom to be exploited [2]. This
revival of time-varying media [3], has in turn boosted the
discovery of new physics associated with time-dependent
optical phenomena, ultimately giving rise to the emerging
field of temporal metamaterials [4,5].
Another research area where structuring matter and
shaping their optical properties is attracting a great deal
of attention is the engineering of thermal emission [68].
As a basic mechanism of heat transfer [9], whereby
an incandescent object at finite temperature emits
(thermal) light [10], thermal radiation is of fundamental
interest. Likewise, it is also the basis of multiple
technological applications including heat and energy
management [11,12], light sources [13], sensing [14],
and communications [15]. In sharp contrast to the
behavior of (non-thermal) light emanating from coherent
sources, thermal light is characterized for displaying a
broadband spectrum and isotropic field distribution, as
well as for being unpolarized and temporally incoherent.
Due to these properties, the control and manipulation
of thermal fields has long been (and continues to
be) a challenging issue. Significant efforts have been
made to explore and stretch out the physical limits of
thermal radiation (imposed by Planck’s [16,17] and
Kirchhoff ’s radiation laws [18,19]) by looking into the
distinctive features occurring at the nanoscale [2023].
Practical implementations have mainly been based on
metamaterials [24], metasurfaces [25], photonic
crystals [26], or subwavelength structures such as
gratings [27], to name a few. In this sense, besides
affording a better far-field thermal emission performance
(e.g., via the so-called thermal extraction schemes [28]),
nanophotonic engineering has stimulated the unveiling of
a plethora of novel near-field thermal effects [29]. Akin
to customary coherent optical sources, the near-field
radiation of thermal emitters greatly differs from that in
the far-field regime [3032]. This is essentially due to the
existence of evanescent modes, which are dominant in
the near-field and negligible in the far-field [33]. Apart
from modifying the spectral distribution, the evanescent
contribution gives access to additional channels over the
frequency-wavevector (ω-k) space, thus strengthening
thermal fields by several orders of magnitude [27,3032].
Just like in the field of nanophotonics, it seems
natural to think that passing from spatially structured to
time-modulated materials could revolutionize the field of
thermal engineering [see Fig. 1]. A clear example comes
through the grating structures [27], whose temporal
analog could similarly open new opportunities [34].
Moreover, the temporal dimension owns in itself
some fundamental attributes tied to the principle of
causality [35]. Nonetheless, the topic of thermal emission
in time-varying media is at a very incipient stage [3638]
and the underlying physics is not fully understood as yet.
Upon this ground, here we put forward a quantum
formalism to address near- and far-field thermal emission
in time-varying media. Noteworthily, this theoretical
formulation would also be extensible to purely quantum
phenomena (e.g., Casimir forces [39] and vacuum
amplification effects [4042]) at finite temperature. Our
formalism allows us to unveil new thermal physics
associated with time-modulated materials, including
fluctuating currents with non-local (space and frequency)
correlations, and far-field thermal emission beyond
the black-body spectrum. In turn, these properties
lead to novel thermal phenomena empowered by the
time-modulation, such as the releasing of fluctuations
trapped within a material body, or the narrowband
near-to-far field thermal linking.
arXiv:2210.05565v1 [physics.optics] 11 Oct 2022
2
Ideal black body
aSpatially structured material
bTime-modulated material
c
enhanced control
Thermal emission
Photon frequency
Thermal emission
Photon frequency
Thermal emission
Photon frequency
time
non-local correlations
beyond black body
dyn. vacuum effects
narrowband spectra
directional emission
polarized propagation
broadband spectra
omnidirectional fields
unpolarized radiation
new physics
FIG. 1. Breakthroughs in thermal emission. a, According to Planck’s law, the broadband emission spectrum (tied
to isotropic and unpolarized thermal radiation) of a black body in thermal equilibrium only depends on the temperature.
b, Thermal emission can be controlled by structuring the matter, enabling narrowband, directive, and polarized radiation.
c, Modulating temporally the optical properties of a medium enables more sophisticated ways to obtain similar effects, yielding
the emergence of new physics, such as non-local correlations, overcoming the black-body spectrum, or dynamical vacuum effects.
A SEMICLASSICAL APPROACH TO THERMAL
RADIATION FROM FLUCTUATING CURRENTS
Theoretical modeling of thermal emission is
typically carried out within the framework of
fluctuational electrodynamics [43]. According to
this semiclassical approach, the emergence of thermal
radiation emanating from a body at temperature
Tcan be understood as a result of the radiation
emitted by the fluctuating electromagnetic (EM)
currents (mathematically characterized by means
of the current density correlations) [see Fig. 2].
The theoretical cornerstone of this formalism is the
fluctuation-dissipation theorem (FDT) [4446], which
provides with a relationship between the correlations
of fluctuating systems and the linear response of the
system associated to its dissipative features:
hj(ρ;ω)·j(ρ0;ω0)ith =4πε0ε00(ρ, ω)~ω2
Θ(ω, T )δ[ωω0]δ[ρρ0],(1)
where the brackets ··ith denote a thermal ensemble
average, Θ(ω, T )=[e~ω/(kBT)1]1, and ε(r, ω) =
ε0(r, ω)+00(r, ω) is the lossy and dispersive permittivity
of the body. A very important feature of Eq. (1) is that
thermally fluctuating currents at different frequencies
and positions are uncorrelated, describing the stochastic
nature of thermal fields.
Once the fluctuating currents are known, the spectral
energy density, S(r;ω) = hE(r;ω)·E(r;ω)ith, at a
given position, r, and frequency, ω, can be directly
found from the connection between fields and currents
E(r;ω) = µ0Rd3ρG(r,ρ, ω)·j(ρ;ω) via the dyadic
Green’s function of the body, G(r,ρ, ω) [see Fig. 2].
Fluctuational electrodynamics is a very successful
theory that has made possible breakthrough advances in
engineering thermal fields with photonic nanostructures.
At the same time, it is a semiclassical theory that does
not allow for the simultaneous modeling of quantum
vacuum and thermal fluctuations, particularly in their
interaction with dynamical systems. In addition, its
extension and applicability to time-varying media is not
rigorously justified [36,37]. In the following, from a
first-principles approach, we introduce a full-quantum
formalism to thermal emission in time-varying media,
which enables the calculation of quantum and thermally
fluctuating current correlations, and thermal fields,
without the need of any additional assumptions beyond
those implicitly set in the Hamiltonian of the system.
FIG. 2. Thermal emission from EM fluctuations.
Schematic representation of the fluctuating density currents
moving inside a hot body. The solid red arrows represent
two particular electric currents which are locally correlated,
releasing so, via the corresponding Green’s function (dashed
red arrows), the emission of thermal fields out the material.
3
A QUANTUM APPROACH TO THERMAL
EMISSION IN TIME-VARYING MEDIA
To establish a general theoretical framework
for extending the study of thermal emission and
the behavior of fluctuating thermal currents and
fields in time-varying media, we make use of
macroscopic quantum electrodynamics [47,48].
Within this framework, instead of bare photons,
one actually deals with elementary excitations,
namely, EM field-matter coupled states modeled
by a continuum of harmonic oscillators [49]. These
modes are described by polaritonic operators,
ˆ
f(r, ωf;t), which, in the Heisenberg picture,
obey the equal-time commutation relations:
[ˆ
f(r, ωf;t),ˆ
f(r0, ω0
f;t)] = [ˆ
f(r, ωf;t),ˆ
f(r0, ω0
f;t)] = 0,
and [ˆ
f(r, ωf;t),ˆ
f(r0, ω0
f;t)] = ˆ
Iδ[rr0]δ[ωfω0
f],
where ˆ
Iis the identity operator.
To describe the dynamical behavior of the time-varying
quantum system we assume a perturbative approach with
a Hamiltonian given by ˆ
H=ˆ
H0+ˆ
HT[41,4750],
where ˆ
H0represents the macroscopic body without
time-modulation,
ˆ
H0=Zd3rZ+
0
f~ωfˆ
f(r, ωf;t)·ˆ
f(r, ωf;t),(2)
while ˆ
HTaccounts for the perturbation describing the
changes induced by the time-modulation,
ˆ
HT=Zd3rˆ
P(r;t)·ˆ
E(r;t).(3)
Here, the polarization field operator, given by ˆ
P(r;t)
Rt
0χ(r, t, τ )ˆ
E(r;τ), is tied to the time-varying
susceptibility of the medium ∆χ(r, t, τ ) [41], and the
electric field operator ˆ
E(r;t) = ˆ
E(+)(r;t) + ˆ
E()(r;t),
whose positive-frequency component reads as,
ˆ
E(+)(r;t) = Z
0
fZd3ρGE(r,ρ, ωf)·ˆ
f(ρ, ωf;t),(4)
with GE(r,ρ, ωf)= ip~ε00(ρ, ωf)ε0(ωf/c)2G(r,ρ, ωf)
being the response function characterizing the
background medium, G(r,ρ, ωf) the dyadic Green’s
function for the unmodulated system, and noticing
that ˆ
E()(r;t)=[ˆ
E(+)(r;t)]. Similar perturbation
Hamiltonians are adopted for modeling other nonlinear
quantum processes [51,52]. Moreover, it is implicitly
assumed that the susceptibility function, χ, is small
enough so that it could be regarded as a perturbation
to the background structure, and does not significantly
affect to the quantization procedure [52].
The emission spectrum, both in the far- and
near-fields, is given by [5357]
S(r;ω) = hˆ
E(+)(r;ω)·ˆ
E(+)(r;ω)ith ,(5)
where ˆ
E(+)(r;ω) = Lω[ˆ
E(r, t)] is the Laplace’s
transform of the electric field operator. By solving
the Heisenberg equations of motion for the polaritonic
operators, i~tˆ
O= [ ˆ
O,ˆ
H], performing an integral in the
complex frequency plane, and rearranging the terms [50],
ˆ
E(+)(r;ω) can be compactly written as follows:
ˆ
E(+)(r;ω) = µ0Zd3ρG(r,ρ, ω)·ˆ
j(ρ;ω),(6)
with the current density operator,
ˆ
j(ρ;ω)=2ωhpπ~ε0ε00(ρ, ω)ˆ
f0iLω[∆˜χ(ρ, t)ˆ
E(ρ;t)]i,(7)
where ˆ
f0ˆ
f(r, ω;t= 0). The first term in
Eq. (7) corresponds to the currents associated with
a system without time-modulation, while the second
term represents the currents excited due to the
time-modulation of the permittivity. In order to
obtain Eq. (7), we have conducted a sharp but routine
assumption, whereby the time-varying susceptibility
exhibits a modulation which actually is local in time,
i.e., ∆χ(r, t, τ) = ∆ ˜χ(r, t)δ[tτ] [3,4,41,58,59].
This simplifies the mathematical treatment, and allows
us to use the aforementioned equal-time commutation
relationships. Despite this particularization, it should
be noted that the formalism is completely general, and
a time-modulation with an arbitrary form would be
feasible with the proper adoption of time-dependent
commutation relations [47].
Equations (5)–(7) provide a quantum framework
for the computation of thermal emission spectra that
is conceptually similar to the semiclassical treatment
sketched above: fluctuating EM currents give rise to
fluctuating thermal fields by means of the corresponding
propagator (the dyadic Green’s function) through the
entire medium. Notwithstanding, the use of a quantum
formulation generalizes the semiclassical treatment,
enabling the evaluation of thermal currents and fields in
time-varying media, the calculation of purely quantum
phenomena such as vacuum amplification effects, and,
ultimately, a sound, self-consistent, and systematic
formulation that directly arises from the assumptions on
the Hamiltonian of the system, without the need of any
semiclassical additions to the theory.
FLUCTUATING CURRENTS IN TIME-VARYING
MACROSCOPIC BODIES
Next, we use this formalism to obtain a general form
of the fluctuating currents excited in a macroscopic
body whose permittivity is modulated in time, providing
an extension to usual forms justified through the
fluctuation-dissipation theorem. To this end, we first
note that Eq. (7) is an implicit equation, where the
current density operator is defined as a function of
4
TABLE I. Fluctuation-dissipation theorem for time-varying systems: First and second-order current density correlations.
hˆ
j
0(ρ;ω)·ˆ
j1(ρ0;ω0)ith =ω0hµ0
πiZV
d3ρ00 Z00ω00 ˜χ(ρ0, ω0ω00)G(ρ0,ρ00, ω00)hˆ
j
0(ρ;ω)·ˆ
j0(ρ00;ω00)ith;
hˆ
j
0(ρ;ω)·ˆ
j2(ρ0;ω0)ith =ω0hµ0
πiZV
d3ρ00 Z00ω00 ˜χ(ρ0, ω0ω00)G(ρ0,ρ00, ω00)hˆ
j
0(ρ;ω)·ˆ
j1(ρ00;ω00)ith
hˆ
j
1(ρ;ω)·ˆ
j1(ρ0;ω0)ith =ωω0hµ0
πi2ZZV
d3˜
ρd3˜
ρ0ZZ d˜ωd˜ω0˜ω˜ω0 ˜χ(ρ, ω ˜ω)∆˜χ(ρ0, ω0˜ω0)
hG(ρ,˜
ρ,˜ω)G(ρ0,˜
ρ0,˜ω0)hˆ
j
0(˜
ρ; ˜ω)·ˆ
j0(˜
ρ0; ˜ω0)ith +G(ρ,˜
ρ,˜ω)G(ρ0,˜
ρ0,˜ω0)hˆ
j0(˜
ρ; ˜ω)·ˆ
j
0(˜
ρ0; ˜ω0)ithi
the electric field operator, which is itself generated
by the current density operator. This fact makes a
clear signature of the sharply intertwined dynamic of
the system. At any rate, such an equation may be
solved iteratively leading to a solution in the form of a
series expansion of current density operators at different
orders [50]:
ˆ
j(r;ω) =
X
n=0
ˆ
jn(r;ω).(8)
Accordingly, the first three elements of the series can
be explicitly written as [50]:
ˆ
j0=ωp4π~ε0ε00(r, ω)ˆ
f(r, ω;t= 0); (9a)
ˆ
j1Zd3ρ0
Z0ω0˜χ(r, ωω0)G(r,ρ0, ω0)ˆ
j0(ρ0;ω0)
+Zd3ρ0
Z0ω0˜χ(r, ωω0)G(r,ρ0, ω0)ˆ
j
0(ρ0;ω0); (9b)
ˆ
j2Zd3ρ0
Z0ω0˜χ(r, ωω0)G(r,ρ0, ω0)ˆ
j1(ρ0;ω0).(9c)
These expressions for the current density operators have
a clear physical meaning: the current density operators
of successive orders result from the fields generated
by the preceding ones. Specifically, a current density
operator of order nat position ρ0and frequency ω0,
i.e., ˆ
jn(ρ0;ω0), generates a field at position rvia
the propagation of the Green’s function G(r,ρ0, ω0).
Roughly speaking, at such a position, the action of the
field over the time-varying susceptibility, ∆ ˜χ(r, ω ω0),
generates a higher-order current at frequency ω, i.e.,
ˆ
jn+1(r, ω). As we will show, the interplay between
sources of different order result in nontrivial correlations
between fluctuating currents at different frequencies and
points of space. Moreover, a crucial aspect of the
current density operators is that they mix creation, ˆ
j
n,
and annihilation, ˆ
jn, polaritonic operators, akin to
Bogoliubov (or squeezing) transformations [60]. The
difference between creation and annihilation operators,
not present in semiclassical treatments, allows for the
prediction of dynamical vacuum effects.
Subsequently, the correlation between fluctuating
currents at different frequencies and points of space can
also be written in a series form:
hˆ
j(r;ω)·ˆ
j(r0;ω0)ith =X
l,m hˆ
j
l(r;ω)·ˆ
jm(r0;ω0)ith.(10)
With this in mind, the corresponding nth-order
correlations can be obtained from a direct evaluation
of hˆ
j
l(r;ω)·ˆ
jm(r0;ω0)ith, where l+m=n,
and ··ith Tr[··· ˆρth], with ˆρth being the
thermal density operator that yields the thermal
fields at a given temperature T[47,48,52].
As expected, the zeroth-order correlation of the current
density, hˆ
j
0·ˆ
j0ith, coincides with the original version of
the FDT given in Eq. (1). In other words, our quantum
formalism correctly recovers the semiclassical case for a
steady (non-time-modulated) system. At the same time,
it generalizes this result via the higher-order correlations.
Indeed, proceeding iteratively, one can find closed form
expressions for such higher-order contributions to the
current density correlations [50]. The corresponding
results for the first and second-order contributions are
presented in the Table I.
Comparing this result with the original form of
the FDT for stationary systems, one may realize
that, even truncating the expansion at the second
order, time-varying media bring new physics to
fluctuational electrodynamics. First feature concerns
to the breakdown of locality, since higher-order
fluctuating currents are correlated at different
frequencies and position of space. For conventional
(non-time-modulated) thermal emitters, the correlations
are local both in position and frequency. This becomes
evident at a glance from the involvement of the Dirac
delta functions [see Eq. (1)], and is physically understood
as a consequence of the random nature of the thermal
fields. However, higher-order terms include integrals
over frequencies and positions. In this manner, the
time-modulation enables the possibility of correlating (or
connecting) different frequencies appearing at different
locations of the material system, thus underscoring its
non-local character and, consequently, the potential to
enhance the coherence of thermal fields.
There is an additional feature that affect to the
photon distribution. Indeed, in the hˆ
j
1·ˆ
j1ith term,
5
the black-body spectrum, Θ(ω, T ), appears inside
a frequency integral. For conventional thermal
emitters, the spectrum of thermal radiation is given by
Ireal(ω, T ) = α(ω)IBB(ω, T ), where α(ω) = (ω)1
is the spectral absorptivity (related to the emissivity
by the Kirchhoff’s radiation law), and IBB Θ(ω, T ),
refers to the black-body emission spectrum. Herein,
Θ(ω, T ) acts as a fixed frequency window that
ultimately sets an upper limit for the radiative heat
transfer. Thus, customary spatial-like nanophotonic
engineering of emission spectra have so far been limited
to the control of the optical absorptivity (or the
emissivity) of materials [61,62], within the limits
imposed by the black-body spectrum [see Fig. 1(b)].
By contrast, our analysis reveals that time-modulated
thermal emitters can affect to the black-body’s photon
distribution, thus making tunable the accessible window
of frequencies [see Fig. 1(c)]. This suggests an additional
and unprecedented way to engineer the density of states.
Another crucial aspect of the hˆ
j
1·ˆ
j1ith term, is
that it contains anti-normally ordered correlations
hˆ
j0·ˆ
j
0ith [63,64], indicating so the eventual occurrence
of vacuum amplifications effects [42]. In fact, this term
is the dominant contribution in the zero-temperature
limit (T0). In this sense, going beyond
a semiclassical approach, our quantum formalism
would allow for unifying quantum photon production
effects (such as the dynamical Casimir effect [40,41],
parametric amplification, ...) and thermal emission
processes. In turn, it paves the way to study vacuum
amplification effects at a finite temperature, which might
be required for the analysis of realistic experimental
configurations. Finally, our quantum formalism for
fluctuating currents sets the basis for calculating
quantum vacuum forces in time-varying media, such as
Casimir forces [39] and quantum friction [6570].
NEW THERMAL EMISSION EFFECTS IN
TIME-VARYING MEDIA
Thus far we have sketched out the theoretical model
of thermally fluctuating currents and their correlations
in time-varying media. Next, we illustrate some of
the main consequences of such a time-modulation in
connection with the emergence of new thermal emission
effects. To this end, we revisit a historical example that
helped initiating the field of nanophotonic engineering
of thermal emission [3032]. It consists of a silicon
carbide (SiC) substrate (z < 0), in contact with
vacuum (z > 0) [see Fig. 3]. The frequency-dependent
permittivity of SiC is described by a Drude-Lorentz
model, so that ε(ω) = ε(ω2
Lω2ω)/(ω2
Tω2ω),
where ε= 6.7, ωL= 29.1 THz, ωT= 23.8 THz,
and γ= 0.14 THz [31], stand, respectively, for the
high-frequency-limit permittivity, the longitudinal and
Thermal emission
t
SiC
SPhPs
Fluctuating
currents
x
z
y
Vacuum
FIG. 3. Thermal emission from a semi-infinite planar
slab of SiC subjected to a harmonic time-modulation.
Schematic depiction of a semi-infinite slab of SiC at
temperature Twith a random distribution of fluctuating
currents moving inside. The horizontal axis represents the
time, so that each section displays a different susceptibility.
transverse optical phonon frequencies, and the damping
factor (or characteristic collision frequency). Because
of such frequency dispersion, a SiC substrate supports
nontrivial far and near-field thermal fluctuations,
including the thermal excitation of surface phonon
polaritons. Here, instead on introducing a grating to
outcouple near-field thermal waves [27], we consider
a time-harmonic modulation of the susceptibility:
˜χ(r, t) = ε0δχ sin Ωt. As we will show, it leads to new
thermal wave phenomena, associated with the release
of strong epsilon-near-zero (ENZ) thermal fluctuations
trapped within the material body.
Evaluating the dyadic Green’s functions
One of the major technical difficulties in evaluating
thermal emission from a time-modulated system lies
in computing the product of multiple dyadic Green’s
functions, which represent the interaction between
fluctuating currents and the radiated fields. Due to
the translational symmetry of the proposed system,
one can take advantage of an angular spectrum
representation [33,55], whereby the dyadic Green’s
function is expressed as a superposition of plane waves:
G(r,ρ, ω) = k2
0
4π2RRVd2κkˆ
G(κx, κy;ω|z, ρz)eik0κkρk,
where k0=ω/c,κk= (κx, κy,0), and ρk=
(ρx, ρy,0). This formalism provides with valuable
physical intuition by separating the modes into
propagating and evanescent, from the character of
their wavevector. Indeed, for each half-space, ki=
k0(κx, κy,pεi(ω)κz,i), so kz,i =k0˜
kz,i =k0pεi(ω)κz,i,
where κz,i =p1κ2
Ri(ω), and κ2
R=κ2
x+κ2
y[32].
Thus, for lossless media (i.e., those where εi(ω) is real),
it is possible to set the usual correspondence of κ2
Rεi
and κ2
R> εi, with propagating and evanescent modes.
摘要:

IncandescenttemporalmetamaterialsJ.EnriqueVazquez-LozanoandI~nigoLiberalyDepartmentofElectrical,ElectronicandCommunicationsEngineering,InstituteofSmartCities(ISC),UniversidadPublicadeNavarra(UPNA),31006Pamplona,Spain(Dated:October12,2022)Regardedasapromisingalternativetospatiallyshapingmatter,tim...

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