1. INTRODUCTION
S-complex asteroids dominate the km-sized near-Earth asteroid (NEA) population and make up
the majority of NEAs at all sizes (DeMeo et al. 2009; Binzel et al. 2019; Ieva et al. 2020). Several
studies have linked these asteroids to ordinary chondrite meteorites (e.g., Gaffey et al. 1993;
Vernazza et al. 2008; Binzel et al. 2009, 2019; DeMeo et al. 2009; Nakamura et al. 2011; Thomas
et al. 2011). Spectral band parameters measured from visible and near infrared (VNIR; 0.45 – 2.5
m) spectra of S-type asteroids are diagnostic of the surface mineralogy of these asteroids (Reddy
et al. 2015). This allows more in-depth and quantitative comparisons of asteroid surfaces and their
proposed meteorite analogs. However, non-compositional effects including grain size, phase
angle, and alteration mechanisms such as space weathering and impact processes, can affect our
ability to make these asteroid-meteorite linkages.
Lunar-style space weathering is an alteration of the surface of airless bodies that occurs due to
long periods of time exposed to the space environment (Gaffey 2010). Nanophase iron particles
created from micrometeorite impacts, solar wind implantation, and other space environment
factors are the main source of the effects of lunar-style space weathering as described in Pieters &
Noble (2016) and references within. These effects have been studied for over 50 years, since before
the Apollo Moon landing (Zeller & Ronca 1967), but shock darkening and impact melt alteration
processes have not been studied as long, with one of the first references being Britt & Pieters
(1989). Whereas studies of space weathering persisted throughout the development of asteroid
science (Hapke 2001; Brunetto et al. 2006; Hiroi et al. 2006; Gaffey 2010; Noguchi et al. 2011),
studies of shock darkening and impact melt only picked up again after the 2013 Chelyabinsk event
(Kohout et al. 2014, 2020a, 2020b; Reddy et al. 2014).
Space weathering affects reflectance spectra of S-type asteroids primarily by lowering the visual
albedo, suppressing absorption bands, and reddening their VNIR spectrum (Hiroi et al. 2006;
Gaffey 2010; Noguchi et al. 2011; Pieters & Noble 2016). Shock darkening also reduces the albedo
and suppresses mineralogical band features, but typically does not redden the spectrum (Kohout
et al. 2014). Shock darkening also changes physical aspects of meteorites and asteroid regolith,
such as porosity and magnetic susceptibility, which cannot be detected through current remote
sensing techniques (Kohout et al. 2014, 2020b, 2020a; Reddy et al. 2014).
Shock darkening observed in the meteorite collection is the result of partial or complete troilite or
FeNi metal melting and mobilization due to impact-related heating. Two stages of shock darkening
are observed at different pressure ranges. The first stage with lower amounts of darkening occurs
at ~40-60 GPa with injection of melts into silicate grains. The second stage occurs at pressures
between 90-150 GPa where bulk melting takes place and troilite and metal are finely dispersed
within the silicate material. The latter is sometimes referred to as impact melt to differentiate the
two phases of shock darkening (Kohout et al. 2020a, 2020b). The two phases cannot effectively
be distinguished with remote sensing and we primarily use the term shock darkening to refer to
both types of impact heating-related darkening of an asteroid surface.
Analysis of shock darkening in meteorites has been used to derive trends in principal component
space that can help distinguish between space weathering and shock darkening (e.g., Binzel et al.